Mixed-Xylene

733 Third Ave. FL 21
New York, NY
10017 USA
TEL: (212) 752-2020
FAX: (212) 821 0025

SAFETY DATA SHEET

1.1 Product identifiers

Product nameXylenes
SynonymsXylenes – Mixed Isomers Xylenes-Ethylbenzene Mixture Xylene Ethylbenzene Mixture

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified usesIndustrial use resulting in manufacture of another substance (use of intermediates)
Solvent Fuel

1.3 Details of the supplier of the safety data sheet

DistributorContinental Industries Group, Inc.
733 Third Avenue Fl. 20
New York, NY, 10017 USA

1.4 Emergency telephone number

Chemtel Phone #1-800-255-3924
International Phone #+01-813-248-0585
Contract #MIS0001728

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

  • GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
  • Flammable liquids Category 3
  • Skin corrosion/irritation Category 2
  • Serious eye damage/eye irritation Category 2B
  • Carcinogenicity Category 2
  • Reproductive toxicity Category 2
  • Specific target organ toxicity (single exposure) Category 3 – Narcotic effects
  • Specific target organ toxicity (single exposure) Category 3 – Respiratory irritation
  • Specific target organ toxicity (single exposure) Category 1
  • Specific target organ toxicity (repeated exposure) Category 1
  • Specific target organ toxicity (repeated exposure) Category 2
  • Aspiration hazard Category 1
  • For the full text of the H-Statements mentioned in this Section, see Section 16.
  • 2.2 GHS Label elements, including precautionary statements

Pictogram

Signal wordDanger
Hazard statement(s)
  • Flammable liquid and vapor
  • May be fatal if swallowed and enters airways
  • Causes skin irritation
  • Causes eye irritation
  • May cause respiratory irritation
  • May cause drowsiness or dizziness
  • Suspected of causing cancer (inhalation)

2. HAZARDS IDENTIFICATION cont’ d

Hazard statement(s)
  • Suspected of damaging fertility or the unborn child
  • Causes damage to organs (lung) (inhalation, oral)Causes damage to organs (nervous system) through prolonged or repeated exposure (inhalation)
  • May cause damage to organs (kidneys, hearing organ (loss of hearing)) through prolonged or repeated exposure
Precautionary statement(s)
  • Obtain special instructions before use.
  • Do not handle until all safety precautions have been read and understood.
  • Keep away from heat, hot surfaces, open flames, sparks. – No smoking.
  • Keep container tightly closed.
  • Ground/bond container and receiving equipment.
  • Use explosion-proof electrical, lighting, ventilating equipment.
  • Use only non-sparking tools.
  • Take precautionary measures against static discharge.
  • Do not breathe gas, mist, vapors.
  • Wash hands, forearms and face thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Wear eye protection, flame retardant protective clothing, protective gloves.
  • Specific treatment (see Section 4.1 of SDS or information on this label).
  • If swallowed: Immediately call doctor, poison center.
  • Do NOT induce vomiting.
  • If inhaled: Remove person to fresh air and keep comfortable for breathing.
  • If on skin: Wash with plenty of water.
  • If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
  • If skin irritation occurs: Get medical advice/attention.
  • If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • If eye irritation persists: Get medical advice/attention.
  • If exposed or concerned: Get medical advice/attention.
  • Get medical advice/attention if you feel unwell.
  • Take off contaminated clothing and wash it before reuse.
  • In case of fire: Use carbon dioxide (CO2), dry chemical, foam, Water spray to extinguish.
  • Store in a well-ventilated place. Keep cool.
  • Store locked up.
  • Dispose of contents and container in accordance with all local, regional, national and international regulations.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS –

Product can accumulate electrostatic charges that may cause fire by electrical discharges.

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances Not applicable

3.2 Mixture

NameCAS No%
Xylenes (o-, m-, p- isomers)1330-20-7>= 80
Ethylbenzene100-41-4<= 20
Toluene108-88-3<= 0.5

4. FIRST AID MEASURES

4.1 Description of first aid measures

First-aid measures generalNever give anything by mouth to an unconscious person. If exposed or concerned: Get medical advice/attention.
First-aid measures after inhalationRemove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contactRemove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention.
4. FIRST AID MEASURES cont’ d
First-aid measures after skin contactRemove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contactIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestionDo NOT induce vomiting. Immediately call a poison center or doctor/physician.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms/injuriesSuspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/injuries after inhalationDanger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. May cause drowsiness or dizziness.
Symptoms/injuries after skin contactRepeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Causes skin irritation.
Symptoms/injuries after eye contactCauses eye irritation. Redness of the eye tissue.
Symptoms/injuries after ingestionMay be fatal if swallowed and enters airways.

4.3 Indication of any immediate medical attention and special treatment needed

No data available

5. FIREFIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing mediaFoam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing mediaDo not use a heavy water stream.

5.2. Special hazards arising from the chemical

Fire hazardFlammable liquid and vapor.
Explosion hazardMay form flammable/explosive vapor-air mixture.
Hazardous decomposition products in case of fireCarbon oxides (CO, CO2). Soot. Toxic fumes.

5.3. Advice for firefighters

Firefighting instructionsUse water spray or fog for cooling exposed containers. Exercise caution when fighting anychemical fire. Prevent fire-fighting water from entering environment.
Protection during firefightingDo not enter fire area without proper protective equipment, including respiratory protection.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Emergency procedures for non-emergency personnelEvacuate unnecessary personnel.
Emergency procedures for emergency respondersVentilate area.

6.2. Methods and material for containment and cleaning up

For containmentTake up liquid spill into absorbent material, e.g.: sand, earth, vermiculite. Do not contaminate ground and surface water.
Methods for cleaning upSoak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collectspillage. Store away from other materials.

6.3. Reference to other sections

See section 8. Exposure controls/personal protection.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Additional hazards when processedHandle empty containers with care because residual vapors are flammable.

7. HANDLING AND STORAGE cont’ d

Precautions for safe handlingWash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No bare lights. No smoking. Take precautionary measures against static discharge.

Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing vapors, mist. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.

 
Hygiene measuresAlways wash hands after handling the product. Wash hands, forearms and face thoroughly prolonged or repeated exposure

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions

Technical measuresExplosion-proof apparatus have to be used. Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, lighting, ventilating equipment. All efforts should be made to prevent any leaks or spills. Storage tanks should be engineered to prevent contact with water resources, as this material could contaminate the water resources. Surface spills can reach groundwater through porous soil or cracked surfaces. The storage tanks should be monitored regularly for leaks. Where spills or leaks are possible, a comprehensive response plan should be developed and implemented.

Keep container tightly closed in a cool, well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, flames, sparks, heat sources. Keep container tightly closed.

 
Incompatible productsStrong oxidizing agents. Strong reducing agents. Strong bases. Strong acids.
Incompatible materialsSources of ignition. Direct sunlight. Heat sources.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Occupational Exposure Limits

Xylenes (o-,m-, p- isomers) (1330-20-7)
USA ACGIHACGIH TWA (ppm)100 ppm
USA ACGIHACGIH STEL (ppm)150 ppm
USA OSHAOSHA PEL (TWA) (mg/m³)435 mg/m³
USA OSHAOSHA PEL (TWA) (ppm)100 ppm
Ethylbenzene (100-41-4)
USA ACGIHACGIH TWA (ppm)20 ppm
USA OSHAOSHA PEL (TWA) (mg/m³)435 mg/m³
USA OSHAOSHA PEL (TWA) (ppm)100 ppm
Toluene (108-88-3)
USA ACGIHACGIH TWA (ppm)20 ppm
USA OSHAOSHA PEL (TWA) (ppm)200 ppm
USA OSHAOSHA PEL (Ceiling) (ppm)300 ppm
USA OSHARemark (OSHA)See OSHA Table Z-2.

8.2 Exposure Controls

Appropriate engineering controlsUse engineering controls, such as enclosed handling systems and local exhaust ventilation, as primary measures to prevent direct exposure to this material. Provide readily accessible eye wash stations and safety showers.
Personal protective equipmentAvoid all unnecessary exposure.
Hand protectionWear Protective gloves.
Eye protectionChemical goggles or safety glasses.
Skin and body protectionWear fire/flame resistant/retardant clothing.
Respiratory protectionWhere exposure through inhalation may occur from use, respiratory protection equipment is recommended. Wear respiratory protection.
Other informationDo not eat, drink or smoke during use.

9. PHYSICAL AND CHEMICAL PROPERTIES cont’ d


9.1. Information on basic physical and chemical properties

Physical stateLiquid
AppearanceClear, colorless liquid.
ColorColorless.
OdorSweet. Aromatic.
Odor threshold0.7 – 40 ppm
pHNot applicable
Relative evaporation rate (butyl acetate=1)No data available
Relative evaporation rate (ether=1)9
Melting pointNo data available
Freezing point-47 °C
Boiling point139 °C
Flash point25 °C Closed cup
Auto-ignition temperature500 – 550 °C
Decomposition temperatureNo data available
Flammability (solid, gas)No data available
Vapor pressure8 mm Hg @ 25°C
Relative vapor density at 20 °C3 – 4 Air = 1
Relative density0.86
Specific gravity / density0.87 g/ml @ 20°C
SolubilityWater: Negligible.
Log Kow3.1
Viscosity, kinematic< 20 cSt
Viscosity, dynamic0.6 cP @25°C
Explosive limits1 – 7 vol %

9.2. Other information

VOC content: 100 %

10. STABILITY AND REACTIVITY

10.1. Reactivity

Flammable liquid and vapor.

10.2. Chemical stability

Stable at ambient temperature and under normal conditions of use.

10.3. Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous polymerization will not occur. Violent explosion may occur when chlorinating xylene with 1,3- dichloro-5,5-dimethyl-2, 4-imidazolidindione (dichlorohydrantoin). The haloimide undergoes immediate self accelerating decomposition.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. Avoid the build-up of electrostatic charge.

10.5. Incompatible materials

Strong acids. Strong bases. Strong oxidizing agents.

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous decomposition products formed under fire conditions: carbon monoxide, carbon dioxide, toxic fumes.

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Likely routes of exposureInhalation. Ingestion. Skin and eye contact.
Acute toxicityNot classified
Inhalation at very high concentrations can be fatal.
Intentional misuse involving repeated and prolonged inhalation exposure to high concentrations of vapor can result in central nervous system damage and eventually death.
Xylene
LD50 oral rat> 3500 (3500 – 4300) mg/kg as mixed xylenes containing ethylbenzene
LD50 dermal rabbit> 4200 mg/kg as mixed xylenes containing ethylbenzene
LC50 inhalation rat21.7 (21.7 – 29.1) mg/l/4h as mixed xylenes containing ethylbenzene
Skin corrosion/irritationCauses skin irritation.
Serious eye damage/irritationCauses eye irritation.
Respiratory or skin sensitizationNot classified
Germ cell mutagenicityNot classified
CarcinogenicitySuspected of causing cancer (inhalation).
Xylenes (o-,m-, p- isomers) (1330-20-7)
IARC group3 – Not classifiable
Ethylbenzene (100-41-4)
IARC group2B – Possibly carcinogenic to humans
Toluene (108-88-3)
IARC group3 – Not classifiable
Reproductive toxicitySuspected of damaging fertility or the unborn child.
Specific target organ toxicity (single exposure)May cause drowsiness or dizziness. May cause respiratory irritation. Causes damage to organs (lung) (inhalation, oral).

Specific target organ toxicity (repeated exposure)

Aspiration hazard

Potential Adverse human health effects and symptoms

Causes damage to organs (nervous system) through prolonged or repeated exposure (inhalation). May cause damage to organs (kidneys, hearing organ (loss of hearing)) through prolonged or repeated exposure.

May be fatal if swallowed and enters airways.

Harmful in contact with skin. Harmful if inhaled.

12. ECOLOGICAL INFORMATION

12.1 Toxicity

Ecology – generalHarmful to aquatic life with long lasting effects.
Xylenes (o-,m-, p- isomers) (1330-20-7)
LC50 fish 113.4 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 13.82 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 22.661 – 4.093 mg/l (Exposure time: 96 h – Species: Oncorhynchus mykiss [static])
EC50 Daphnia 20.6 mg/l (Exposure time: 48 h – Species: Gammarus lacustris)
Ethylbenzene (100-41-4)
LC50 fish 111.0 – 18.0 mg/l (Exposure time: 96 h – Species: Oncorhynchus mykiss [static])
EC50 Daphnia 11.8 – 2.4 mg/l (Exposure time: 48 h – Species: Daphnia magna)
EC50 other aquatic organisms 14.6 mg/l (Exposure time: 72 h – Species: Pseudokirchneriella subcapitata)
LC50 fish 24.2 mg/l (Exposure time: 96 h – Species: Oncorhynchus mykiss [semi-static])
EC50 other aquatic organisms 2> 438 mg/l (Exposure time: 96 h – Species: Pseudokirchneriella subcapitata)
Toluene (108-88-3)
LC50 fish 115.22 – 19.05 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 15.46 – 9.83 mg/l (Exposure time: 48 h – Species: Daphnia magna [Static])
EC50 other aquatic organisms 1> 433 mg/l (Exposure time: 96 h – Species: Pseudokirchneriella subcapitata)
LC50 fish 212.6 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 211.5 mg/l (Exposure time: 48 h – Species: Daphnia magna)
EC50 other aquatic organisms 212.5 mg/l (Exposure time: 72 h – Species: Pseudokirchneriella subcapitata [static])

12. ECOLOGICAL INFORMATION cont’ d

12.2. Persistence and degradability

Xylene

Persistence and degradabilityNot established.

12.3. Bioaccumulative potential

Xylene

Log Kow3.1
Bioaccumulative potentialNot established.
Xylenes (o-,m-, p- isomers) (1330-20-7)
BCF fish 10.6 – 15
Log Pow2.77 – 3.15
Ethylbenzene (100-41-4)
BCF fish 115
Log Pow3.118
Toluene (108-88-3)
Log Pow2.65
12.4.

No additional information available

12.5. Other adverse effects

Other information: Avoid release to the environment.

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste disposal recommendationsDispose in a safe manner in accordance with local/national regulations. Dispose of contents and container in accordance with all local, regional, national and international regulations.
Additional informationHandle empty containers with care because residual vapors are flammable.
Ecology – waste materialsAvoid release to the environment.

14. TRANSPORT INFORMATION

NON-HAZARDOUS WHEN SHIPPED IN SMALL QUANTITIES IN A UN4G

PACKAGE (WITH A STRONG OUTER PACKAGE) UNDER DOT 49 CFR 173.150(b)(3).

OTHERWISE, IT IS CLASS 3, PG III UN 1993

US Transport (DOT) for Bulk Shipments (Non-Bulk Shipments May Differ)

Transport document description

UN or NA Number

Proper Shipping Name

Primary Hazard Class Packing Group

Reportable Quantities (RQ)*

*It is the shipper’s responsibility to determine whether an RQ must be reported for each individual shipment.

Hazard labels

UN1993, Flammable liquids, n.o.s. (contains xylene isomers, ethylbenzene), 3, PGIII

UN1993

Flammable liquids, n.o.s. (contains xylene isomers, ethylbenzene)

3 – Flammable liquid

PGIII

Ethylbenzene 1000 lbs (454 kg), Mixed Xylenes 100 lbs (45.4 kg), Toluene 1000 lbs (454 kg)

14. TRANSPORT INFORMATION

Transport by sea (IMDG)

Transport document description

UN Number

Proper Shipping Name

Primary Hazard Class

Packing Group

Hazard labels (IMDG)

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Cargo name listed in 46 CFR 30.25, Table 30.25-1

Cargo name listed in 46 CFR 153, Table 1

Air transport (IATA)

Transport document description

UN Number

Proper Shipping Name

Primary Hazard Class

Packing Group

Hazard labels (IATA)

UN1993, FLAMMABLE LIQUID, N.O.S., 3, PGIII

UN1993

Flammable liquid, n.o.s.

3 – Flammable liquids

PGIII

Product Name: Xylenes/Ethylbenzene (10% or more) mixture Pollution Category: Y

Ship Type: 2

Xylenes/Ethylbenzene (10% or more) mixture

Xylenes, Ethylbenzene (10% or more) mixture

UN1993, Flammable liquid, n.o.s., 3, PGIII

UN1993

Flammable liquid, n.o.s.

3 – Flammable Liquids

PGIII

15. REGULATORY INFORMATION

15.1. US Federal regulations EPA TSCA Status

All components of this product are listed or excluded from listing on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory.

SARA Section 313 Supplier Notification

This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372:

CAS numberChemical nameConcentration
1330-20-7Xylenes (o-, m-, p- isomers)>= 80%
100-41-4Ethylbenzene<= 20%

This information must be included in all Safety Data Sheets that are copied and distributed for this product. For additional information, see 40 CFR §372.45 Notification About Toxic Chemicals.

SARA Section 311/312 Hazard ClassesFire hazard
Chronic health hazard
Acute health hazard

15.2. International regulations

CANADA

Xylene

WHMIS Classification Class B Division 2 – Flammable Liquid

Class D Division 2 Subdivision A – Very toxic material causing other toxic effects Class D Division 2 Subdivision B – Toxic material causing other toxic effects

15. REGULATORY INFORMATION
 

National inventories

Listed on the Canadian DSL (Domestic Sustances List)

15.3. US State regulations

Ethylbenzene (100-41-4)

U.S. – California – Proposition 65 – Carcinogens ListYes
U.S. – California – Proposition 65 – Developmental ToxicityNo
U.S. – California – Proposition 65 – Reproductive Toxicity – FemaleNo
U.S. – California – Proposition 65 – Reproductive Toxicity – MaleNo
No significance risk level (NSRL)54 µg/day (inhalation)
Toluene (108-88-3)
U.S. – California – Proposition 65 – Carcinogens ListNo
U.S. – California – Proposition 65– Developmental ToxicityYes
U.S. – California – Proposition 65– Reproductive Toxicity – FemaleYes
U.S. – California – Proposition 65– Reproductive Toxicity – MaleNo

16. OTHER INFORMATION

NFPA (National Fire Protection Association)
NFPA health hazard2
NFPA fire hazard3
NFPA reactivity0
HMIS III Rating
Health2*
Flammability3
Physical Hazard0
Personal ProtectionSee section 8 of SDS

Further information

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Continental Industries Group, Inc. shall not be held liable for any damage resulting from handling or from contact with the above product.

16. OTHER INFORMATION cont’ d

US OSHA LABEL as specified under 29 CFR §1910.1200 (f)

Xylene

Emergency telephone number

DangerChemtel Phone #1-800-255-3924
Flammable liquid and vaporInternational Phone #+01-813-248-0585
May be fatal if swallowed and enters airwaysContract #MIS0001728
  • Causes skin irritation Causes eye irritation
  • May cause respiratory irritation May cause drowsiness or dizziness
  • Suspected of causing cancer (inhalation) Suspected of damaging fertility or the unborn child Causes damage to organs (lung) (inhalation, oral)
  • Causes damage to organs (nervous system) through prolonged or repeated exposure (inhalation)
  • May cause damage to organs (kidneys, hearing organ (loss of hearing)) through prolonged or repeated exposure
  • Obtain special instructions before use.
  • Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, open flames, sparks. – No smoking. Keep container tightly closed.
  • Ground/bond container and receiving equipment.
  • Use explosion-proof electrical, lighting, ventilating equipment. Use only non-sparking tools.
  • Take precautionary measures against static discharge. Do not breathe gas, mist, vapors.
  • Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Wear eye protection, flame retardant protective clothing, protective gloves. Specific treatment (see Section 4.1 of SDS or information on this label).
  • If swallowed: Immediately call doctor, poison center. Do NOT induce vomiting.
  • If inhaled: Remove person to fresh air and keep comfortable for breathing. If on skin: Wash with plenty of water.
  • If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
  • If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
  • If exposed or concerned: Get medical advice/attention. Get medical advice/attention if you feel unwell.
  • Take off contaminated clothing and wash it before reuse.
  • In case of fire: Use carbon dioxide (CO2), dry chemical, foam, Water spray to extinguish. Store in a well-ventilated place. Keep cool.
  • Store locked up.
  • Dispose of contents and container in accordance with all local, regional, national and international regulations.
  • Supplemental Information: Other hazards not contributing to the classification
  • Product can accumulate electrostatic charges that may cause fire by electrical discharges.

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